All-solid-state lithium batteries (ASSLBs) with higher energy density and improved safety have been regarded as an alternative to the state-of-the-art Li-ion batteries.
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							Lithium-sulfur all-solid-state battery (Li-S ASSB) technology has attracted attention as a safe, high-specific-energy (theoretically 2600 Wh kg −1), durable, and low-cost
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							Considering the safety issues of Li ion batteries, an all-solid-state polymer electrolyte has been one of the promising solutions. Achieving a Li ion conductivity of a solid-state electrolyte
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							Recently, a new Li 3 HoBr 6 was synthesized by a solid-state reaction [65]. The Li 3 HoBr 6 has an electrochemical window of 1.5–3.3 V and a high Li + conductivity of 1.1 mS
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							Among lithium secondary batteries, all solid-state thin film batteries (TFBs) are of particular interest, due to their great adaptability to different applications [1], and enhanced
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							A stable anode-free all-solid-state battery (AF-ASSB) with sulfide-based solid-electrolyte (SE) (argyrodite Li 6 PS 5 Cl) is achieved by tuning wetting of lithium metal on
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							Figure 1: A schematic comparison between the structure of a traditional lithium-ion battery (left) and an all-solid-state battery (right), during discharge. Research Endeavors and Obstacles. The transition from liquid to
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							With the development of electric mobility, the requirements for battery energy density and safety are rapidly rising [1, 2].State-of-the-art liquid-based batteries pose leakage
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							Solid-state lithium batteries are on the threshold of commercialization as an alternative to liquid electrolyte batteries. Glassy or amorphous solid electrolytes could bring
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							An all-solid-state battery with a lithium metal anode is a strong candidate for surpassing conventional lithium-ion battery capabilities. However, undesirable Li dendrite
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							Lithium-ion batteries (LIBs) have been the undisputed leading technology in electrochemical energy storage since they were commercialized in 1991. All-solid-state
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							Whereas numerous ''beyond Li-ion battery'' chemistries and architectures are being developed in parallel 12,13,14, all-solid-state lithium–sulfur (Li–S) batteries have been
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							Solid state batteries (SSBs) are utilized an advantage in solving problems like the reduction in failure of battery superiority resulting from the charging and discharging cycles
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							To compare these with a basic reference system, we present an all-solid-state battery using only a lithium metal anode, β-Li 3 PS 4 solid electrolyte and Li(Ni 0.6 Co 0.2 Mn
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							Herein, we analyze the real cases of different kinds of all-solid-state lithium batteries with high energy density to understand the current status, including all-solid-state lithium-ion batteries, all-solid-state lithium metal
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							The authors present a FeCl3 cathode design that enables all-solid-state lithium-ion batteries with a favourable combination of low cost, improved safety and good performance.
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							A pressing need for enhancing lithium-ion battery (LIB) performance exists, particularly in ensuring reliable operation under extreme cold conditions. All-solid-state
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							This Perspective provides a fundamental overview of all-solid-state Li–S batteries by delving into the underlying redox mechanisms of solid-state sulfur, placing a specific emphasis on key
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							All-solid-state lithium batteries coupled with transition metal sulfide cathodes have gained significant attention due to their high energy density and exceptional safety.
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							All-solid-state lithium batteries (ASSLBs) are considered promising alternatives to current lithium-ion batteries as their use poses less of a safety risk. However, the fabrication
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							The all-solid-state lithium-ion battery has a structure in which a positive electrode layer, a solid electrolyte layer, and a negative electrode layer are laminated. The solid electrolyte also fulfills
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							This review introduces solid electrolytes based on sulfide/polymer composites which are used in all-solid-state lithium batteries, describing the use of polymers as plasticizer,
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							Build a High-Performance All-Solid-State Lithium Battery through Introducing Competitive Coordination Induction Effect in Polymer-Based Electrolyte. Tenghui Wang, Tenghui Wang. Center of Materials Science and
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							Solid-state batteries are commonly acknowledged as the forthcoming evolution in energy storage technologies. Recent development progress for these rechargeable
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							The Mg16Bi84 anode interlayer and F-rich cathode interlayer provide a general solution for all-solid-state lithium-metal batteries to achieve high energy and fast charging
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							Composite solid-state electrolytes for all solid-state lithium batteries: progress, challenges and outlook Wan et al. 175 designed and tested an integrated all-solid-state
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							All-solid-state lithium batteries (ASSLBs) have recently received substantial attention because of their unprecedented safety and high theoretical energy density. 1 To
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							An all-solid-state battery with a lithium metal anode is a strong candidate for surpassing conventional lithium-ion battery capabilities. However, undesirable Li dendrite
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							ConspectusAll-solid-state lithium batteries have received considerable attention in recent years with the ever-growing demand for efficient and safe energy storage technologies.
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							In-depth mechanistic insights inform the fabrication of an all-solid-state, Co-free lithium battery with good performance and cyclability.
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							Build a High-Performance All-Solid-State Lithium Battery through Introducing Competitive Coordination Induction Effect in Polymer-Based Electrolyte. Tenghui Wang,
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							All-solid-state batteries (ASSBs) are among the remarkable next-generation energy storage technologies for a broad range of applications, including (implantable) medical
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							An all-solid-state battery with a lithium metal anode is a strong candidate for surpassing conventional lithium-ion battery capabilities. However, undesirable Li dendrite
View moreHerein, we analyze the real cases of different kinds of all-solid-state lithium batteries with high energy density to understand the current status, including all-solid-state lithium-ion batteries, all-solid-state lithium metal batteries, and all-solid-state lithium–sulfur batteries.
All-solid-state lithium-air batteries with inorganic solid electrolytes represent a kind of safe and high energy density batteries.
For applications requiring safe, energy-dense, lightwt. batteries, solid-state lithium-sulfur batteries are an ideal choice that could surpass conventional lithium-ion batteries. Nevertheless, there are challenges specific to practical solid-state lithium-sulfur batteries, beyond the typical challenges inherent to solid-state batteries in general.
Several possible research directions are suggested as well. The all-solid-state lithium batteries using solid electrolytes are considered to be the new generation of devices for energy storage. Recent advances in this kind of rechargeable batteries have brought them much closer to a commercial reality.
The first generation of all-solid-state lithium batteries used in electric vehicles was manufactured by the France's Bolloré group in 2011. But the advanced all-solid-state batteries are still under the stage of research and development. Few data from the industries are reported.
Nature 637, 846–853 (2025) Cite this article With promises for high specific energy, high safety and low cost, the all-solid-state lithium–sulfur battery (ASSLSB) is ideal for next-generation energy storage 1, 2, 3, 4, 5.
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