A Mn-based sodium-containing layered oxide, P′2-type Na2/3MnO2, is revisited as a positive electrode material for sodium-ion batteries, and factors affecting its
View moreUsing the new positive electrode. The team developed a positive electrode for sodium batteries using Na 2 FeS 2 that can be charged and discharged for more than 300 cycles. This is down to the unique crystal structure of the Na 2
View moreHerein, we report a Na-rich material, Na 2 SeO 3 with an unconventional layered structure as a positive electrode material in NIBs for the first time. This material can deliver a discharge capacity of 232 mAh g −1 after activation, one of the highest capacities from sodium-based positive electrode materials. X-ray photoelectron spectroscopy
View moreAbstract Sodium-ion batteries have been emerging as attractive technologies for large-scale electrical energy storage and conversion, owing to the natural
View morePolyanion compounds offer a playground for designing prospective electrode active materials for sodium-ion storage due to their structural diversity and chemical variety. Here, by combining a NaVPO4F composition and KTiOPO4-type framework via a low-temperature (e.g., 190 °C) ion-exchange synthesis approach, we develop a high-capacity and high-voltage positive electrode
View moreMedium-entropy materials (MEMs) and high-entropy materials (HEMs) have recently emerged as promising cathode materials for sodium-ion batteries (SIBs), especially
View morePolyanion compounds offer a playground for designing prospective electrode active materials for sodium-ion storage due to their structural diversity and chemical variety. NATURE COMMUNICATIONS
View moreSodium secondary batteries have attracted widespread attention as a next-generation energy storage technology, owing to the low cost and ubiquitous availability of Na resources [1].The chemical similarities between Na and Li imply that the extensively studied electrode materials for Li batteries provide a superior reference library for research on Na
View moreRedox-active polymers provide opportunities for developing advanced electrode materials for sodium-ion batteries because of their structural diversity and flexibility, surface functionalities and tenability, and low cost. This
View moreIn the past three years, P2-Na x MeO 2 has become an extensively studied positive electrode material for sodium batteries.4,43,58–63 All of the P2-Na x MeO 2 materials examined as positive electrode materials for sodium batteries so far contain cobalt, manganese, or titanium ions,11,20,64 except for P2-Na x VO 2.65 It is thought that this originates from the
View moreElectrode materials with different nano-dimensional architectures and unique structures, such as those with a hollow structure or a porous structure, have been deliberately designed to provide satisfactory performance for SIBs. 7, 8, 9 Modification strategies, such as conductive layer coating and surface etching, are subsequently conducted to address distinct
View moreE = 2.08–1.78 V at 350 °C. During the processes of discharging, all the active materials are in the state of molten, as the result, only Na 2 S x (x ≥ 3) which have the melting points below 300 °C are permitted to be produced. In the initial state, both sulfur and sodium polysulfide (Na 2 S 5) are coexisted at the voltage of 2.08 V due to their immiscible nature.
View moreHere we demonstrate Na 4 Mn 9 O 18 as a sodium intercalation positive electrode material for an aqueous electrolyte energy storage device. A simple solid-state synthesis route was used to produce this material, which was then tested electrochemically in a 1 M Na 2 SO 4 electrolyte against an activated carbon counter electrode using cyclic
View moretional binder to enable positive electrode manufacturing of SIBs and to overall reduce battery manufacturing costs. Introduction The cathode is a critical player determining the performance and cost of a battery.[1,2] Over the years, several types of cathode materials have been reported for sodium-ion batteries (SIBs),
View moreOn the basis of material abundance, rechargeable sodium batteries with iron- and manganese-based positive electrode materials are the ideal candidates for large-scale batteries. In this review, iron- and manganese-based electrode materials, oxides, phosphates, fluorides, etc, as positive electrodes for rechargeable sodium batteries are reviewed.
View moreElectrode properties of Na2−xFe2(SO4)3 in Na cell. (a) Galvanostatic charging and discharging profiles of Na2−xFe2(SO4)3 cathode cycled between 2.0 and 4.5 V at a
View moreNew layered metal oxides as positive electrode materials for room-temperature sodium-ion batteries Mu Lin-Qin (穆林沁), Hu Yong-Sheng (胡勇胜), Chen Li-Quan (陈立泉) Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China
View moreFurthermore, we demonstrate that a positive electrode containing Li2-xFeFe(CN)6⋅nH2O (0 ≤ x ≤ 2) active material coupled with a Li metal electrode and a LiPF6-containing organic-based
View moreFurthermore, the sodium storage properties of nanostructures can be further improved through tailoring their size, shape, and composition. 31, 32, 33 In particular, the combination of nanostructured active materials with conductive species, such as carbonaceous materials and conductive polymers, represents a promising and effective approach to improve
View moreadapting positive electrode materials of LIBs, including Na super ionic conductor structures 7, layered oxides 5,8, tunnel-structured oxides 9 and fluorophosphates 10, for Na þ intercalation.
View moreA Mn-based sodium-containing layered oxide, P′2-type Na 2/3 MnO 2, is revisited as a positive electrode material for sodium-ion batteries, and factors affecting its electrochemical performances are examined.The cyclability of Na 2/3 MnO 2 is remarkably improved by increasing the lower cut-off voltage during cycling even though the reversible
View moreBattery Preparation. The electrochemical properties of Na 3 V 2 (PO 4) 2 F 3 were examined by using 2032 coin-type batteries, in which the positive electrode consisted of 85 wt % Na 3 V 2 (PO 4) 2 F 3 /C composite, 8 wt % Super P carbon, and 7 wt % poly-(tetrafluoroethylene) (PTFE) binder. Sodium metal supported on a current collector was used
View moreIn this article, we review advances in layered sodium transition metal oxides as positive electrode materials for batteries. Layered sodium transition metal oxides, Na x MeO 2
View moreElectrochemistry Communications. Volume 45, August 2014, Pages 63-66. Short communication. Na 2 MnSiO 4 as a positive electrode material for sodium secondary batteries using an ionic liquid electrolyte. Ball mill assisted synthesis of Na 3 MnCO 3 PO 4 nanoparticles anchored on reduced graphene oxide for sodium ion battery cathodes
View moreTo verify the feasibility of an NFS-H-based positive electrode for practical applications, we assembled an all-iron-sulfur sodium-ion cell with presodiated FeS-based
View moreA Mn-based sodium-containing layered oxide, P′2-type Na 2/3 MnO 2, is revisited as a positive electrode material for sodium-ion batteries, and factors affecting its
View moreSnapshot on Negative Electrode Materials for Potassium-Ion Batteries. The performance of hard carbons, the renowned negative electrode in NIB (Irisarri et al., 2015), were also investigated in KIB a detailed study, Jian et al. compared the electrochemical reaction of Na + and K + with hard carbon microspheres electrodes prepared by pyrolysis of sucrose (Jian et al., 2016).The
View moreThis article reviews recent advancements and trends in layered sodium transition metal oxides as positive electrode materials for Na-ion batteries. The global demand for advanced energy storage technology is rapidly increasing.
However, the performance of sodium-ion electrode materials has not been competitive with that of lithium-ion electrode materials. Here we present sodium manganese hexacyanomanganate (Na 2 Mn II [Mn II (CN) 6]), an open-framework crystal structure material, as a viable positive electrode for sodium-ion batteries.
The development of high-capacity and high-voltage electrode materials can boost the performance of sodium-based batteries. Here, the authors report the synthesis of a polyanion positive electrode active material that enables high-capacity and high-voltage sodium battery performance.
Alcantara, R., Jimenez-Mateos, J.M., Lavela, P., et al.: Carbon black: a promising electrode material for sodium-ion batteries. Electrochem.
Energy Mater. 1, 333–336 (2011) Xia, X., Dahn, J.R.: NaCrO 2 is a fundamentally safe positive electrode material for sodium-ion batteries with liquid electrolytes. Electrochem. Solid State Lett. 15, A1–A4 (2012) Doeff, M.M., Richardson, T.J., Kepley, L.: Lithium insertion processes of orthorhombic Na x MnO 2 -based electrode materials. J.
The O3-type lithium transition metal oxides, LiMeO 2, have been intensively studied as positive electrode materials for lithium batteries, and O3-LiCoO 2, 10 Li [Ni 0.8 Co 0.15 Al 0.05]O 2, 26, 27 and Li [Ni 1/3 Mn 1/3 Co 1/3] O 2 28, 29 are often utilized for practical Li-ion batteries.
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