(A) Standard Gibbs free energy changes of the possible reactions versus the temperature. The diagram was produced using HSC Chemistry® 7 software. (B) Schematic showing proposed sulfurization
View moreThe review consolidates findings on enhanced specific capacitance, improved rate capability, extended cycle life, and increased energy density achieved through
View moreHere, MnOS@NSC with MnOS microspheres encapsulated in N, S co-doped carbon shells with a core–shell structure synthesized by a sulfurization method has been reported to be a potential anode material for LIBs with high capacity,
View moreThe effects of the sulfurization process in the preparation on the morphology, chemical structure, specific surface area, and ORR catalytic activity of the final material are investigated. The experimental results show that the surface of the S-Co-N/C material tends to be rough due to the sulfurization reaction of the metal elements.
View moreThis review analyzes the sulfurization reactions of various transition metal compounds in Li-S batteries and their profound impact on electrochemical performance.
View moreThe 16-electron electrochemical charge transfer reaction with a working voltage of about 2.2 V allows a specific energy density of 2600 Wh kg −1 for Li–S batteries. With optimal configuration,
View moreSulfurization synthesis of a new anode material for Li-ion batteries: understanding the role of sulfurization in lithium ion conversion reactions and promoting lithium storage performance† Journal of Materials Chemistry A ( IF 11.9) Pub Date : 2019-08-27 00:00:00, DOI: 10.1039/c9ta08394d
View moreOrganic matter sulfurization reactions can occur on the timescale of just hours to days, according to the paper, "Organic carbon burial during OAE2 driven by changes in the locus of organic matter
View morea Guangzhou Key Laboratory for Surface Chemistry of Energy Materials, New Energy Research Institute, College of Environment and Energy, South China University of Technology, Guangzhou 510006, China E-mail:
View moreTo further study the effect of the sulfurization process on the microstructure of the S-Co-N/C catalyst, TEM images of the obtained two samples in Figure 2 were also tested. The cobalt elements of the S-Co-N/C-I
View moreThe synthesized (CoFeNiMnCu) 9 S 8 high-entropy sulfide catalyst achieves elemental equilibrium and exhibits an optimized surface charge distribution. During oxygen-based battery
View moreLithium-sulfur (Li-S) batteries have garnered significant attention for their exceptional energy density, positioning them as a promising solution for next-generation
View moreSulfurization reaction energies of 24 metal sulfide (M-S) systems including M = Li, Na, K, Mg, Ca, Sr, Ba, Zn, Al, Ti, Mn, Fe, Co, Ni, Cu, Mo, Rh, Pd, Ir, Pt, La, Ce, Th, and U are evaluated using generalized gradient approximation (GGA) and GGA + U calculations.Our results indicate that unlike metal oxides and halides, GGA reaction energy predictions can be
View more@article{Qin2019SulfurizationSO, title={Sulfurization synthesis of a new anode material for Li-ion batteries: understanding the role of sulfurization in lithium ion conversion reactions and promoting lithium storage performance}, author={Yanmin Qin and Zhongqing Jiang and Liping Guo and Jianlin Huang and Zhong-Jie Jiang and Meilin Liu}, journal={Journal of
View moreDesigning lead-carbon batteries (LCBs) as an upgrade of LABs is a significant area of energy storage research. The successful implementation of LCBs can facilitate several new technological innovations in important sectors such as the automobile industry [[9], [10], [11]].Several protocols are available to assess the performance of a battery for a wide range of
View moreWhen it occurs, the battery will struggle to receive, hold and produce a charge. Battery Details. An everyday acid battery has a sequence of oppositely charged lead and lead oxide plates. The substances divide cells.
View moreThis study develops a new pretreatment technique that is applied prior to the flotation concentration of PGMs in autocatalysts. This method utilizes electroless Cu plating followed by sulfurization.
View moreBy elucidating the sulfurization process with the assistance of advanced characterization techniques, we aim to reveal the true active sites and intrinsic catalytic pathways of sulfur redox electrocatalysts, offering new insights into the design of advanced catalysts for
View moreSo, to increase the power and energy densities, a new hybrid device called a supercapattery was created by combining a battery-grade electrode with a capacitive-type electrode. The remarkable electrochemical properties and conductivity of transition metal sulphides have made them a hot topic in the search for battery-grade materials that could be
View moresulfurization of Nd 2O 3. At above 973 K, the decomposition of Nd 2(SO 4) 3 resulted in the decrease of Nd leaching efficiency. Furthermore, the required roasting time and Fe 2(SO 4) 3Æ5H 2O dosage to obtain the same Nd leaching efficiency were different for the sulfurization of Nd 2O 3 and NdFeO 3 at 973 K, and the sulfurization of NdFeO
View moreBismuth (Bi) anodes have been widely investigated for potential application in sodium-ion batteries (SIBs) due to their ultrahigh theoretical volumetric capacity (3800 mAh cm −3) and suitable sodiation potential (0.5–0.7 V).Unfortunately, either Bi or Bi-based compounds still face tricky challenges of unsatisfying reversible capacity (<350 mAh g −1) and inferior initial
View moreA discharge capacity of 784 mAh g-1 can be obtained when the battery was tested at the current density of 1 C (544 mA g-1). this metal-organic frameworks sulfurization route also shows good
View more4 70 1a for 56 pure metal oxides and detailed in Table S1. The differences in [P S2 /P SO2] crit between 71 pure species and real materials can be accounted for by solution thermodynamics (Figure E2), as 72 presented in Supplemental Materials. Unlike P O2 for oxide reduction alone, and P S2 for sulfide 73 reduction alone, the P S2 /P SO2 ratio for sulfidation of an oxide can
View morePhase-engineered heterostructures of Mo2C by plasma-assisted selenization and sulfurization processes toward excellent hydrogen evolution reaction Nano Energy ( IF 16.8) Pub Date : 2023-12-26, DOI: 10.1016/j.nanoen.2023.109235
View moreA trace-sulfurization strategy creates a regional Bi/Bi 2 S 3 hetero-interface confined within a S-doped carbon shell (TS-Bi/C), enhancing interfacial charge transfer and thereby improving
View moreRecently, increasing interest has focused on the sulfurization of these catalysts in polysulfide-rich environments, a process that holds great potential for enhancing their efficiency. This review analyzes the sulfurization reactions of various transition metal compounds in Li–S batteries and their profound impact on electrochemical performance.
View moreThe experimental results show that the surface of the S-Co-N/C material tends to be rough due to the sulfurization reaction of the metal elements. University, Xi''an, China, 2 Key Laboratory
View moreThermal conductive silica gel and power batteries for new energy vehicles. As a high-end thermal conductive composite material, the thermal conductive silica gel has been widely used in new energy
View moreat the electrode plate. The catalyst accelerates the transfer of electrons on the electrode plate, achieving higher current density, converting more electrical energy into chemical energy, and finally separating hydrogen from the cathode through several processes. Therefore, improving the efficiency of electron and ion transfer in an electrolyte,
View moreSulfurized Synthesis of a New Anode Material for Li-Ion Batteries: Understanding the Role of Sulfurization in Lithium Ion Conversion Reactions and Promoting
View morecontinue to break through the energy density of commercial ion batteries. Therefore, the development of new high energy density battery systems is imperative.[9–14] Lithium-sulfur (Li S) batteries have become one of the most promising energy storage systems due to their high theoretical specific capacity of 1675 mAh g 1 and high energy density of
View moreHere we develop and implement mixed ionic–electronic conductors (MIECs) in sulfur cathodes to replace conventional solid electrolytes and invoke conversion reactions at
View moreRecently, increasing interest has focused on the sulfurization of these catalysts in polysulfide-rich environments, a process that holds great potential for enhancing their efficiency. This review analyzes the sulfurization reactions of various transition metal compounds in Li–S batteries and their profound impact on electrochemical performance.
Lithium–sulfur (Li–S) batteries have garnered significant attention for their exceptional energy density, positioning them as a promising solution for next-generation energy storage. A critical factor in their performance is the use of transition metal inorganic compound electrocatalysts, prized for their distinctive catalytic properties.
The conversion reaction between sulfur and lithium generates various Li 2 S n that are soluble in common organic electrolytes.
Sulfurization was found to modify the surface chemistry and structure of activated carbon, resulting in improved electrochemical performance. In energy storage applications, it expands the surface area and adds more active sites, resulting in increased charge storage capacity and quicker charge/discharge rates .
Moreover, their good electrical conductivity accelerates the conversion kinetics of sulfur species. Some noble metals (e.g., Pt and Ir), transition metals (e.g., Fe, Co, and Ni), and alloys have been introduced to Li–S batteries. The principal issue that decreases the catalytic activities of metals is structural stability.
For instance, sulfur particles were incor-porated into carbon black, carbon nanotubes, and graphene to improve the sulfur utilization in Mg –S batteries.165–170Li et al.169 reported a N,Co co-doped carbon framework as an e ective S
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